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Microsoft rolled out a trial version of this option back in August last year, but that was only supported in a limited number of countries. Now the option works worldwide, and also has built-in HD calling support.
To use Skype in Outlook.com, you’ll need to install a browser plug-in. You’ll also need to have merged your Microsoft and Skype accounts, though if you’ve used Skype at all in the past year, that’s likely to have happened already.